Bi2Se3 Nanostructured Thin Films as Perspective Anodes for Aqueous Rechargeable Lithium-Ion Batteries

Vitalijs Lazarenko; Yelyzaveta Rublova; Raimonds Meija; Jana Andzane; Vanda Voikiva; Artis Kons; Anatolijs Sarakovskis; Arturs Viksna; Donats Erts

doi:10.3390/batteries8100144

Bi₂Se₃ Nanostructured Thin Films as Perspective Anodes for Aqueous Rechargeable Lithium-Ion Batteries

Vitalijs Lazarenko, Yelyzaveta Rublova, Raimonds Meija, Jana Andzane, Vanda Voikiva, Artis Kons, Anatolijs Sarakovskis, Arturs Viksna (Corresponding Author), Donats Erts (Corresponding Author)

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

15 Downloads (Pure)

Abstract

In recent years, aqueous rechargeable lithium-ion batteries (ARLIBs) have attracted attention as an alternative technology for electrical storage. One of the perspective battery anode materials for application in ARLIBs is Bi₂Se₃, which has already shown good perspectives in the application of conventional lithium-ion batteries (LIBs) that use organic electrolytes. In this study, the electrochemical properties of Bi₂Se₃ thin films with two different layers on the electrode surface—the solid electrolyte interphase (SEI) and the Bi₂O₃ layer—were investigated. The results of this work show that the formation of the SEI layer on the surface of Bi₂Se₃ thin films ensures high diffusivity of Li⁺, high electrochemical stability, and high capacity up to 100 cycles, demonstrating the perspectives of Bi₂Se₃ as anode material for ARLIBs.

Original language	English
Article number	144
Journal	Batteries
Volume	8
Issue number	10
DOIs	https://doi.org/10.3390/batteries8100144
Publication status	Published - Oct 2022
Externally published	Yes

Keywords*

anode
aqueous rechargeable lithium-ion batteries (ARLIBs)
bismuth oxide (BiO)
bismuth selenide (BiSe)
electrochemical performance
solid electrolyte interphase (SEI)

Field of Science*

1.3 Physical sciences
1.4 Chemical sciences

Publication Type*

1.1. Scientific article indexed in Web of Science and/or Scopus database

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.3390/batteries8100144Licence: CC BY

Bi2Se3 Nanostructured Thin FilmsFinal published version, 4.01 MBLicence: CC BY

Cite this

@article{c8f970a0c3db4ebd86a1a2897f34a5af,

title = "Bi2Se3 Nanostructured Thin Films as Perspective Anodes for Aqueous Rechargeable Lithium-Ion Batteries",

abstract = "In recent years, aqueous rechargeable lithium-ion batteries (ARLIBs) have attracted attention as an alternative technology for electrical storage. One of the perspective battery anode materials for application in ARLIBs is Bi2Se3, which has already shown good perspectives in the application of conventional lithium-ion batteries (LIBs) that use organic electrolytes. In this study, the electrochemical properties of Bi2Se3 thin films with two different layers on the electrode surface—the solid electrolyte interphase (SEI) and the Bi2O3 layer—were investigated. The results of this work show that the formation of the SEI layer on the surface of Bi2Se3 thin films ensures high diffusivity of Li+, high electrochemical stability, and high capacity up to 100 cycles, demonstrating the perspectives of Bi2Se3 as anode material for ARLIBs.",

keywords = "anode, aqueous rechargeable lithium-ion batteries (ARLIBs), bismuth oxide (BiO), bismuth selenide (BiSe), electrochemical performance, solid electrolyte interphase (SEI)",

author = "Vitalijs Lazarenko and Yelyzaveta Rublova and Raimonds Meija and Jana Andzane and Vanda Voikiva and Artis Kons and Anatolijs Sarakovskis and Arturs Viksna and Donats Erts",

note = "Funding Information: This research was funded by the European Regional Development Fund Project (ERDF) No. 1.1.1.1/19/A/139. Y.R. acknowledges the support of post-doctoral ERDF project No. 1.1.1.2/VIAA/4/20/694. V.L. also acknowledges the support of “Strengthening of the capacity of doctoral studies at the University of Latvia within the framework of the new doctoral model”, identification No. 8.2.2.0/20/I/006. A.S. acknowledges the support from the Institute of Solid State Physics, University of Latvia, which, as the Center of Excellence, has received funding from the European Union{\textquoteright}s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2. Publisher Copyright: {\textcopyright} 2022 by the authors.",

year = "2022",

month = oct,

doi = "10.3390/batteries8100144",

language = "English",

volume = "8",

journal = "Batteries",

issn = "2313-0105",

publisher = "Molecular Diversity Preservation International",

number = "10",

}

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T1 - Bi2Se3 Nanostructured Thin Films as Perspective Anodes for Aqueous Rechargeable Lithium-Ion Batteries

AU - Lazarenko, Vitalijs

AU - Rublova, Yelyzaveta

AU - Meija, Raimonds

AU - Andzane, Jana

AU - Voikiva, Vanda

AU - Kons, Artis

AU - Sarakovskis, Anatolijs

AU - Viksna, Arturs

AU - Erts, Donats

N1 - Funding Information: This research was funded by the European Regional Development Fund Project (ERDF) No. 1.1.1.1/19/A/139. Y.R. acknowledges the support of post-doctoral ERDF project No. 1.1.1.2/VIAA/4/20/694. V.L. also acknowledges the support of “Strengthening of the capacity of doctoral studies at the University of Latvia within the framework of the new doctoral model”, identification No. 8.2.2.0/20/I/006. A.S. acknowledges the support from the Institute of Solid State Physics, University of Latvia, which, as the Center of Excellence, has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2. Publisher Copyright: © 2022 by the authors.

PY - 2022/10

Y1 - 2022/10

N2 - In recent years, aqueous rechargeable lithium-ion batteries (ARLIBs) have attracted attention as an alternative technology for electrical storage. One of the perspective battery anode materials for application in ARLIBs is Bi2Se3, which has already shown good perspectives in the application of conventional lithium-ion batteries (LIBs) that use organic electrolytes. In this study, the electrochemical properties of Bi2Se3 thin films with two different layers on the electrode surface—the solid electrolyte interphase (SEI) and the Bi2O3 layer—were investigated. The results of this work show that the formation of the SEI layer on the surface of Bi2Se3 thin films ensures high diffusivity of Li+, high electrochemical stability, and high capacity up to 100 cycles, demonstrating the perspectives of Bi2Se3 as anode material for ARLIBs.

AB - In recent years, aqueous rechargeable lithium-ion batteries (ARLIBs) have attracted attention as an alternative technology for electrical storage. One of the perspective battery anode materials for application in ARLIBs is Bi2Se3, which has already shown good perspectives in the application of conventional lithium-ion batteries (LIBs) that use organic electrolytes. In this study, the electrochemical properties of Bi2Se3 thin films with two different layers on the electrode surface—the solid electrolyte interphase (SEI) and the Bi2O3 layer—were investigated. The results of this work show that the formation of the SEI layer on the surface of Bi2Se3 thin films ensures high diffusivity of Li+, high electrochemical stability, and high capacity up to 100 cycles, demonstrating the perspectives of Bi2Se3 as anode material for ARLIBs.

KW - anode

KW - aqueous rechargeable lithium-ion batteries (ARLIBs)

KW - bismuth oxide (BiO)

KW - bismuth selenide (BiSe)

KW - electrochemical performance

KW - solid electrolyte interphase (SEI)

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U2 - 10.3390/batteries8100144

DO - 10.3390/batteries8100144

M3 - Article

AN - SCOPUS:85140446254

SN - 2313-0105

VL - 8

JO - Batteries

JF - Batteries

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M1 - 144

ER -