Characteristics of the SEI-Layer Formations on the Bi2Se3 Anode in LiNO3 and NaNO3 Solutions by Electrochemical Impedance Spectroscopy

Yelyzaveta Rublova; Vitalijs Lazarenko; Raimonds Meija; Vanda Voikiva; Anna Skrastina; Jana Andzane; Arturs Viksna; Donats Erts

doi:10.1109/IWIS57888.2022.9975111

Characteristics of the SEI-Layer Formations on the Bi₂Se₃Anode in LiNO₃and NaNO₃Solutions by Electrochemical Impedance Spectroscopy

Yelyzaveta Rublova (Corresponding Author)
, Vitalijs Lazarenko
, Raimonds Meija
, Vanda Voikiva
, Anna Skrastina
, Jana Andzane
, Arturs Viksna
, Donats Erts

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review

1 Citation (Scopus)

Abstract

Dissolved O2 and CO2 in aqueous electrolytes lead to the formation of oxides and carbonates on the electrode surface. The formation of the SEI layer on the BbSe3 anode was investigated by cyclic voltammetry and EIS methods. The SEI layer on the surface of the Bi2 Se3 anode, in addition to soluble carbonates and oxides, also includes water-insoluble (BiO)2 CO3. The composition and concentration of the electrolyte affect the electrochemical characteristics of the formed SEI layer. During cycling the resistance and capacitance of the SEI layer gradually decreased for both LiNO3 and NaNO3 which showed the instability in the SEI layer and the dissolving of soluble components.

Original language	English
Title of host publication	International Workshop on Impedance Spectroscopy, IWIS 2022
Subtitle of host publication	Proceedings
Publisher	Institute of Electrical and Electronics Engineers Inc.
Pages	85-87
Number of pages	3
ISBN (Electronic)	979-835031039-9
DOIs	https://doi.org/10.1109/IWIS57888.2022.9975111
Publication status	Published - 2022
Externally published	Yes
Event	15th International Workshop on Impedance Spectroscopy (IWIS 2022) - Chemnitz, Germany Duration: 27 Sept 2022 → 30 Sept 2022 Conference number: 15 https://www.tu-chemnitz.de/etit/messtech/iwis/

Publication series

Name	Proceedings of International Workshop on Impedance Spectroscopy

Workshop

Workshop	15th International Workshop on Impedance Spectroscopy (IWIS 2022)
Abbreviated title	IWIS 2022
Country/Territory	Germany
City	Chemnitz
Period	27/09/22 → 30/09/22
Internet address	https://www.tu-chemnitz.de/etit/messtech/iwis/

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords*

aqueous lithium-ion batteries
aqueous sodium-ion batteries
bismuth selenide
solid electrolyte interface
thin films

Field of Science*

1.4 Chemical sciences
1.3 Physical sciences

Publication Type*

3.1. Articles or chapters in proceedings/scientific books indexed in Web of Science and/or Scopus database

Access to Document

10.1109/IWIS57888.2022.9975111

Cite this

Rublova, Y., Lazarenko, V., Meija, R., Voikiva, V., Skrastina, A., Andzane, J., Viksna, A., & Erts, D. (2022). Characteristics of the SEI-Layer Formations on the Bi₂Se₃Anode in LiNO₃and NaNO₃Solutions by Electrochemical Impedance Spectroscopy. In International Workshop on Impedance Spectroscopy, IWIS 2022: Proceedings (pp. 85-87). (Proceedings of International Workshop on Impedance Spectroscopy). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/IWIS57888.2022.9975111

Rublova, Yelyzaveta ; Lazarenko, Vitalijs ; Meija, Raimonds et al. / Characteristics of the SEI-Layer Formations on the Bi₂Se₃Anode in LiNO₃and NaNO₃Solutions by Electrochemical Impedance Spectroscopy. International Workshop on Impedance Spectroscopy, IWIS 2022: Proceedings. Institute of Electrical and Electronics Engineers Inc., 2022. pp. 85-87 (Proceedings of International Workshop on Impedance Spectroscopy).

@inproceedings{dcf95bb3a95541a0853ad822ace995b5,

title = "Characteristics of the SEI-Layer Formations on the Bi2Se3 Anode in LiNO3 and NaNO3 Solutions by Electrochemical Impedance Spectroscopy",

abstract = "Dissolved O2 and CO2 in aqueous electrolytes lead to the formation of oxides and carbonates on the electrode surface. The formation of the SEI layer on the BbSe3 anode was investigated by cyclic voltammetry and EIS methods. The SEI layer on the surface of the Bi2 Se3 anode, in addition to soluble carbonates and oxides, also includes water-insoluble (BiO)2 CO3. The composition and concentration of the electrolyte affect the electrochemical characteristics of the formed SEI layer. During cycling the resistance and capacitance of the SEI layer gradually decreased for both LiNO3 and NaNO3 which showed the instability in the SEI layer and the dissolving of soluble components.",

keywords = "aqueous lithium-ion batteries, aqueous sodium-ion batteries, bismuth selenide, solid electrolyte interface, thin films",

author = "Yelyzaveta Rublova and Vitalijs Lazarenko and Raimonds Meija and Vanda Voikiva and Anna Skrastina and Jana Andzane and Arturs Viksna and Donats Erts",

note = "Korespondējo{\v s}ais autors ir norādīts Web of Science, bet nav norādīts oriģinālpublikācijā. Funding Information: This research was funded by the European Regional Development Fund (project no. 1.1.1.2/VIAA/4/20/694, {\textquotedblleft}Optimization of solid-electrolyte interphase layer of hybrid carbon nanotube-Bi2Se3 anode electrodes for improved performance of Li-ion batteries{\textquotedblright}) Funding Information: V. L. thanks the support of {\textquotedblleft}Strengthening of the capacity of doctoral studies at the University of Latvia within the framework of the new doctoral model{\textquotedblright}, identification No. 8.2.2.0/20/1/006.{\textquotedblright}. Publisher Copyright: {\textcopyright} 2022 IEEE.; 15th International Workshop on Impedance Spectroscopy (IWIS 2022), IWIS 2022 ; Conference date: 27-09-2022 Through 30-09-2022",

year = "2022",

doi = "10.1109/IWIS57888.2022.9975111",

language = "English",

series = "Proceedings of International Workshop on Impedance Spectroscopy",

publisher = "Institute of Electrical and Electronics Engineers Inc.",

pages = "85--87",

booktitle = "International Workshop on Impedance Spectroscopy, IWIS 2022",

address = "United States",

url = "https://www.tu-chemnitz.de/etit/messtech/iwis/",

}

Rublova, Y, Lazarenko, V, Meija, R, Voikiva, V, Skrastina, A, Andzane, J, Viksna, A & Erts, D 2022, Characteristics of the SEI-Layer Formations on the Bi₂Se₃Anode in LiNO₃and NaNO₃Solutions by Electrochemical Impedance Spectroscopy. in International Workshop on Impedance Spectroscopy, IWIS 2022: Proceedings. Proceedings of International Workshop on Impedance Spectroscopy, Institute of Electrical and Electronics Engineers Inc., pp. 85-87, 15th International Workshop on Impedance Spectroscopy (IWIS 2022), Chemnitz, Germany, 27/09/22. https://doi.org/10.1109/IWIS57888.2022.9975111

Characteristics of the SEI-Layer Formations on the Bi₂Se₃Anode in LiNO₃and NaNO₃Solutions by Electrochemical Impedance Spectroscopy. / Rublova, Yelyzaveta (Corresponding Author); Lazarenko, Vitalijs; Meija, Raimonds et al.
International Workshop on Impedance Spectroscopy, IWIS 2022: Proceedings. Institute of Electrical and Electronics Engineers Inc., 2022. p. 85-87 (Proceedings of International Workshop on Impedance Spectroscopy).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review

TY - GEN

T1 - Characteristics of the SEI-Layer Formations on the Bi2Se3 Anode in LiNO3 and NaNO3 Solutions by Electrochemical Impedance Spectroscopy

AU - Rublova, Yelyzaveta

AU - Lazarenko, Vitalijs

AU - Meija, Raimonds

AU - Voikiva, Vanda

AU - Skrastina, Anna

AU - Andzane, Jana

AU - Viksna, Arturs

AU - Erts, Donats

N1 - Conference code: 15

PY - 2022

Y1 - 2022

N2 - Dissolved O2 and CO2 in aqueous electrolytes lead to the formation of oxides and carbonates on the electrode surface. The formation of the SEI layer on the BbSe3 anode was investigated by cyclic voltammetry and EIS methods. The SEI layer on the surface of the Bi2 Se3 anode, in addition to soluble carbonates and oxides, also includes water-insoluble (BiO)2 CO3. The composition and concentration of the electrolyte affect the electrochemical characteristics of the formed SEI layer. During cycling the resistance and capacitance of the SEI layer gradually decreased for both LiNO3 and NaNO3 which showed the instability in the SEI layer and the dissolving of soluble components.

AB - Dissolved O2 and CO2 in aqueous electrolytes lead to the formation of oxides and carbonates on the electrode surface. The formation of the SEI layer on the BbSe3 anode was investigated by cyclic voltammetry and EIS methods. The SEI layer on the surface of the Bi2 Se3 anode, in addition to soluble carbonates and oxides, also includes water-insoluble (BiO)2 CO3. The composition and concentration of the electrolyte affect the electrochemical characteristics of the formed SEI layer. During cycling the resistance and capacitance of the SEI layer gradually decreased for both LiNO3 and NaNO3 which showed the instability in the SEI layer and the dissolving of soluble components.

KW - aqueous lithium-ion batteries

KW - aqueous sodium-ion batteries

KW - bismuth selenide

KW - solid electrolyte interface

KW - thin films

UR - https://www.scopus.com/pages/publications/85145437564

UR - https://www-webofscience-com.db.rsu.lv/wos/alldb/full-record/WOS:000904772500019

U2 - 10.1109/IWIS57888.2022.9975111

DO - 10.1109/IWIS57888.2022.9975111

M3 - Conference contribution

AN - SCOPUS:85145437564

T3 - Proceedings of International Workshop on Impedance Spectroscopy

SP - 85

EP - 87

BT - International Workshop on Impedance Spectroscopy, IWIS 2022

PB - Institute of Electrical and Electronics Engineers Inc.

T2 - 15th International Workshop on Impedance Spectroscopy (IWIS 2022)

Y2 - 27 September 2022 through 30 September 2022

ER -

Rublova Y, Lazarenko V, Meija R, Voikiva V, Skrastina A, Andzane J et al. Characteristics of the SEI-Layer Formations on the Bi₂Se₃Anode in LiNO₃and NaNO₃Solutions by Electrochemical Impedance Spectroscopy. In International Workshop on Impedance Spectroscopy, IWIS 2022: Proceedings. Institute of Electrical and Electronics Engineers Inc. 2022. p. 85-87. (Proceedings of International Workshop on Impedance Spectroscopy). doi: 10.1109/IWIS57888.2022.9975111