Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids

N.M.A.N. Daud; Eduards Baķis; J. P. Hallett; C. C. Weber; T. Welton

doi:10.1039/c7cc06112a

Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids

N.M.A.N. Daud, Eduards Baķis, J. P. Hallett, C. C. Weber, T. Welton (Corresponding Author)

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

We present a study of the reactions of aldehydes in ionic liquids which gives evidence for the spontaneous formation of N-heterocyclic carbenes in ionic liquids based on 1,3-dialkyl substituted imidazolium cations from the lack of a deuterium isotope effect on the reaction of these ionic liquids with aldehydes.

Original language	English
Pages (from-to)	11154-11156
Number of pages	3
Journal	Chemical Communications
Volume	53
Issue number	81
DOIs	https://doi.org/10.1039/c7cc06112a
Publication status	Published - 2017
Externally published	Yes

Keywords*

ionic liquid
carbene
imidazole derivative
heterocyclic compound
chemical structure
reaction analysis

Field of Science*

1.4 Chemical sciences

Publication Type*

1.1. Scientific article indexed in Web of Science and/or Scopus database

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10.1039/c7cc06112a

https://pubs.rsc.org/en/content/articlelanding/2017/CC/C7CC06112A

Cite this

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title = "Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids",

abstract = "We present a study of the reactions of aldehydes in ionic liquids which gives evidence for the spontaneous formation of N-heterocyclic carbenes in ionic liquids based on 1,3-dialkyl substituted imidazolium cations from the lack of a deuterium isotope effect on the reaction of these ionic liquids with aldehydes.",

keywords = "ionic liquid, carbene, imidazole derivative, heterocyclic compound, chemical structure, reaction analysis",

author = "N.M.A.N. Daud and Eduards Baķis and Hallett, {J. P.} and Weber, {C. C.} and T. Welton",

note = "Funding Information: We would like to thank the Universiti Malaysia Perlis and Ministry of Higher Education Malaysia for the provision of a scholarship (NMAND). Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

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doi = "10.1039/c7cc06112a",

language = "English",

volume = "53",

pages = "11154--11156",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "81",

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TY - JOUR

T1 - Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids

AU - Daud, N.M.A.N.

AU - Baķis, Eduards

AU - Hallett, J. P.

AU - Weber, C. C.

AU - Welton, T.

N1 - Funding Information: We would like to thank the Universiti Malaysia Perlis and Ministry of Higher Education Malaysia for the provision of a scholarship (NMAND). Publisher Copyright: © 2017 The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - We present a study of the reactions of aldehydes in ionic liquids which gives evidence for the spontaneous formation of N-heterocyclic carbenes in ionic liquids based on 1,3-dialkyl substituted imidazolium cations from the lack of a deuterium isotope effect on the reaction of these ionic liquids with aldehydes.

AB - We present a study of the reactions of aldehydes in ionic liquids which gives evidence for the spontaneous formation of N-heterocyclic carbenes in ionic liquids based on 1,3-dialkyl substituted imidazolium cations from the lack of a deuterium isotope effect on the reaction of these ionic liquids with aldehydes.

KW - ionic liquid

KW - carbene

KW - imidazole derivative

KW - heterocyclic compound

KW - chemical structure

KW - reaction analysis

UR - http://www.scopus.com/inward/record.url?scp=85031089805&partnerID=8YFLogxK

U2 - 10.1039/c7cc06112a

DO - 10.1039/c7cc06112a

M3 - Article

C2 - 28890962

AN - SCOPUS:85031089805

SN - 1359-7345

VL - 53

SP - 11154

EP - 11156

JO - Chemical Communications

JF - Chemical Communications

IS - 81

ER -

Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids

Abstract

Keywords*

Field of Science*

Publication Type*

Access to Document

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