Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer

Rufus Smits; Yelena Goncharenko; Iveta Vesere; Baiba Skrivele; Oksana Petrichenko; Brigita Vigante; Marina Petrova; Aiva Plotniece; Gunars Duburs

doi:10.1016/j.jfluchem.2011.04.008

Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer

Rufus Smits, Yelena Goncharenko, Iveta Vesere, Baiba Skrivele, Oksana Petrichenko, Brigita Vigante, Marina Petrova, Aiva Plotniece, Gunars Duburs

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1H)-pyridone- 5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS).

Original language	English
Pages (from-to)	414-419
Number of pages	6
Journal	Journal of Fluorine Chemistry
Volume	132
Issue number	6
DOIs	https://doi.org/10.1016/j.jfluchem.2011.04.008
Publication status	Published - Jun 2011
Externally published	Yes

Keywords*

3,4-Dihydropyridone
Fluorous cationic amphiphiles
Self-assembly

Field of Science*

1.4 Chemical sciences

Publication Type*

1.1. Scientific article indexed in Web of Science and/or Scopus database

Access to Document

10.1016/j.jfluchem.2011.04.008

Cite this

@article{9b067cf110084e48898e663afe871e12,

title = "Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer",

abstract = "The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1H)-pyridone- 5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS).",

keywords = "3,4-Dihydropyridone, Fluorous cationic amphiphiles, Self-assembly",

author = "Rufus Smits and Yelena Goncharenko and Iveta Vesere and Baiba Skrivele and Oksana Petrichenko and Brigita Vigante and Marina Petrova and Aiva Plotniece and Gunars Duburs",

note = "Funding Information: This work was supported by the ESF project No. 2009/0197/1DP/1.1.1.2.0/09/APIA/VIAA/014. ",

year = "2011",

month = jun,

doi = "10.1016/j.jfluchem.2011.04.008",

language = "English",

volume = "132",

pages = "414--419",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

number = "6",

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TY - JOUR

T1 - Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer

AU - Smits, Rufus

AU - Goncharenko, Yelena

AU - Vesere, Iveta

AU - Skrivele, Baiba

AU - Petrichenko, Oksana

AU - Vigante, Brigita

AU - Petrova, Marina

AU - Plotniece, Aiva

AU - Duburs, Gunars

N1 - Funding Information: This work was supported by the ESF project No. 2009/0197/1DP/1.1.1.2.0/09/APIA/VIAA/014.

PY - 2011/6

Y1 - 2011/6

N2 - The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1H)-pyridone- 5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS).

AB - The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1H)-pyridone- 5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS).

KW - 3,4-Dihydropyridone

KW - Fluorous cationic amphiphiles

KW - Self-assembly

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U2 - 10.1016/j.jfluchem.2011.04.008

DO - 10.1016/j.jfluchem.2011.04.008

M3 - Article

AN - SCOPUS:79957974300

SN - 0022-1139

VL - 132

SP - 414

EP - 419

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 6

ER -

Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer

Abstract

Keywords*

Field of Science*

Publication Type*

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