When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

Elina Priede; Eduards Baķis; Andris Zicmanis

doi:10.1055/s-0034-1379018

When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

Elina Priede (Corresponding Author), Eduards Baķis, Andris Zicmanis

Research output: Contribution to journal › Letter › peer-review

8 Citations (Scopus)

Abstract

Structurally diverse aromatic and aliphatic ionic liquids have been prepared via anion metathesis utilizing alkylammonium chlorides and trimethyl phosphate. Excellent oxygen-containing functional-group tolerance in preparation of potentially greener dimethyl phosphate ionic liquids has been demonstrated. For the first time, this method has been employed in the synthesis of dicationic imidazolium-based ionic liquids possessing a dimethyl phosphate counterion, providing a simple, direct route towards structurally novel products of high purity.

Original language	English
Article number	st-2014-d0499-l
Pages (from-to)	2447-2450
Number of pages	4
Journal	Synlett
Volume	25
Issue number	17
DOIs	https://doi.org/10.1055/s-0034-1379018
Publication status	Published - 22 Oct 2014
Externally published	Yes

Keywords*

anion metathesis
dicationic ionic liquids
dimethyl phosphate
monocationic ionic liquids

Field of Science*

1.4 Chemical sciences

Publication Type*

1.1. Scientific article indexed in Web of Science and/or Scopus database

Access to Document

10.1055/s-0034-1379018

https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0034-1379018

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title = "When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids",

abstract = "Structurally diverse aromatic and aliphatic ionic liquids have been prepared via anion metathesis utilizing alkylammonium chlorides and trimethyl phosphate. Excellent oxygen-containing functional-group tolerance in preparation of potentially greener dimethyl phosphate ionic liquids has been demonstrated. For the first time, this method has been employed in the synthesis of dicationic imidazolium-based ionic liquids possessing a dimethyl phosphate counterion, providing a simple, direct route towards structurally novel products of high purity.",

keywords = "anion metathesis, dicationic ionic liquids, dimethyl phosphate, monocationic ionic liquids",

author = "Elina Priede and Eduards Baķis and Andris Zicmanis",

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doi = "10.1055/s-0034-1379018",

language = "English",

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T1 - When Chlorides are the Most Reactive

T2 - A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

AU - Priede, Elina

AU - Baķis, Eduards

AU - Zicmanis, Andris

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart New York.

PY - 2014/10/22

Y1 - 2014/10/22

N2 - Structurally diverse aromatic and aliphatic ionic liquids have been prepared via anion metathesis utilizing alkylammonium chlorides and trimethyl phosphate. Excellent oxygen-containing functional-group tolerance in preparation of potentially greener dimethyl phosphate ionic liquids has been demonstrated. For the first time, this method has been employed in the synthesis of dicationic imidazolium-based ionic liquids possessing a dimethyl phosphate counterion, providing a simple, direct route towards structurally novel products of high purity.

AB - Structurally diverse aromatic and aliphatic ionic liquids have been prepared via anion metathesis utilizing alkylammonium chlorides and trimethyl phosphate. Excellent oxygen-containing functional-group tolerance in preparation of potentially greener dimethyl phosphate ionic liquids has been demonstrated. For the first time, this method has been employed in the synthesis of dicationic imidazolium-based ionic liquids possessing a dimethyl phosphate counterion, providing a simple, direct route towards structurally novel products of high purity.

KW - anion metathesis

KW - dicationic ionic liquids

KW - dimethyl phosphate

KW - monocationic ionic liquids

UR - http://www.scopus.com/inward/record.url?scp=84937346784&partnerID=8YFLogxK

U2 - 10.1055/s-0034-1379018

DO - 10.1055/s-0034-1379018

M3 - Letter

AN - SCOPUS:84937346784

SN - 0936-5214

VL - 25

SP - 2447

EP - 2450

JO - Synlett

JF - Synlett

IS - 17

M1 - st-2014-d0499-l

ER -

When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

Abstract

Keywords*

Field of Science*

Publication Type*

Access to Document

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